开始时间: 04/22/2022 持续时间: 11 weeks
所在平台: CourseraArchive 课程类别: 化学 大学或机构: University of Minnesota(美国明尼苏达大学) 授课老师: Christopher J. Cramer |
课程主页: https://www.coursera.org/course/thermodynamics
课程评论:没有评论
This introductory physical chemistry course examines the connections between molecular properties and the behavior of macroscopic chemical systems.
Topics covered:
Week 1:
Overview of thermodynamics and its importance and utility.Week 2:
Molecular energy levels from quantum mechanics.
Ideal gases; Equations of state; PV diagrams.Week 3:
Gases and liquids; Corresponding states.
Dispersion; Intermolecular interactions; Real gases.
Boltzmann probability and connection to energy; Ensemble properties.Week 4:
Heat capacity; Partition functions.
Atomic and molecular partition functions; Connections to quantum mechanics (statistical thermodynamics).
Electronic and translational partition function for gases; Rovibrational partition functions.Week 5:
Heat capacities.
First law of Thermodynamics; Energy; PV Work; State functions.Week 6:
Adiabaticity; Reversibility; Heat and work.
Enthalpy; Heat capacity redux; Heat of transition.
Enthalpy of chemical reaction; Heat of formation; Standard-state enthalpy.
Second law; Order/disorder; Entropy.Week 7:
Spontaneity and entropy; Statistical thermodynamics and entropy; Reversibility.
Entropy and the interconversion of heat and work; Entropy and the partition function.
Third law; Temperature limits; Perfect crystals; Phase transitions.Week 8:
Experimental determination of third-law entropies; Standard-state entropy.
Helmholtz and Gibbs free energies; Ensemble conditions.
Maxwell relations; Ideal gas state functions; Independent variables.
Gaseous standard state; Gibbs-Helmholtz equation; Fugacity.
This introductory physical chemistry course examines the connections between molecular properties and the behavior of macroscopic chemical systems.
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