开始时间: 04/22/2022 持续时间: 未知
所在平台: MIT公开课 课程类别: 化学 大学或机构: ocw |
课程主页: http://ocw.mit.edu/courses/chemistry/5-80-small-molecule-spectroscopy-and-dynamics-fall-2008
课程评论:没有评论
The goal of this course is to illustrate the spectroscopy of small molecules in the gas phase: quantum mechanical effective Hamiltonian models for rotational, vibrational, and electronic structure; transition selection rules and relative intensities; diagnostic patterns and experimental methods for the assignment of non-textbook spectra; breakdown of the Born-Oppenheimer approximation (spectroscopic perturbations); the stationary phase approximation; nondegenerate and quasidegenerate perturbation theory (van Vleck transformation); qualitative molecular orbital theory (Walsh diagrams); the notation of atomic and molecular spectroscopy.