Non-Equilibrium Applications of Statistical Thermodynamics

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课程主页: https://www.coursera.org/archive/stats-thermo-non-equilibrium-applications

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Transport Properties of Ideal Gases
Spectroscopic Methods
Chemical Kinetics and Combustion

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Course 5 of Statistical Thermodynamics explores three different applications of non-equilibrium statistical thermodynamics. The first is the transport behavior of ideal gases, with some discussion of transport in dense gases and liquids. It starts with simple estimates of the transport properties of an ideas gas. It then introduces the Boltzmann Equation and describes the Chapman-Enskog solution of that equation in order to obtain the transport properties. It closes with a discussion of practical sources of transport properties. Spectroscopic methods have become increasingly common as a way of determining the thermodynamic state of a system. Here we present the underlying concepts of the subject and explores how spectroscopy can be used to determine thermodynamic and flow properties. Chemical kinetics are important in a variety of fluid/thermal applications including combustion, air quality, fuel cells and material processing. Here we cover the basics of chemical kinetics, with a particular focus on combustion. It starts with some definitions, including reaction rate and reaction rate constant. It then explores methods for determining reaction rate constants. Next, systems of reactions, or reaction mechanisms, are explored, including the oxidation of hydrogen and hydrocarbon fuels. Finally, computational tools for carrying out kinetic calculations are explored.

统计热力学的非平衡应用:统计热力学的第5课探讨了非平衡统计热力学的三种不同应用。 首先是理想气体的传输行为,并讨论了在稠密气体和液体中的传输。它从简单估计创意气体的传输特性开始。然后,它介绍了Boltzmann方程,并描述了该方程的Chapman-Enskog解,以获得输运性质。最后讨论运输特性的实际来源。 光谱法已成为确定系统热力学状态的一种越来越普遍的方法。在这里,我们介绍了该主题的基本概念,并探讨了如何使用光谱学确定热力学和流动特性。 化学动力学在包括燃烧,空气质量,燃料电池和材料加工在内的各种流体/热应用中都很重要。在这里,我们介绍了化学动力学的基础知识,尤其着重于燃烧。它从一些定义开始,包括反应速率和反应速率常数。然后探讨确定反应速率常数的方法。接下来,探索反应系统或反应机理,包括氢和碳氢化合物燃料的氧化。最后,探索了用于进行动力学计算的计算工具。

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