Fundamentals of Macroscopic and Microscopic Thermodynamics

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Program Introduction
Macroscopic Thermodynamics
Microscopic Thermodynamics

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Course 1 first explores the basics of both macroscopic and microscopic thermodynamics from a postulatory point of view. In this view, the meaning of temperature, thermodynamic pressure and chemical potential are especially clear and easy to understand. In addition , the development of the Fundamental Relation and its various transformations leads to a clear path to property relations and to the concept of ensembles needed to understand the relationship between atomic and molecular structural properties and macroscopic properties. We then explore the relationship between atomic and molecular structure and macroscopic properties by taking a statistical point of view. Using a postulatory approach, the method for doing this is made clear. This leads to the development of the partition function which describes the distribution of molecular quantum states as a function of the independent, macroscopic thermodynamic properties.

宏观和微观热力学的基础知识:课程1首先从假定的角度探讨宏观和微观热力学的基础。根据这种观点,温度,热力学压力和化学势的含义特别清晰并且易于理解。此外,基本关系的发展及其各种转变为特性关系提供了一条清晰的道路,并为理解原子和分子结构特性与宏观特性之间的关系所需的整体概念提供了一条清晰的道路。然后,我们从统计学的角度探讨原子和分子结构与宏观性质之间的关系。使用假定方法,可以清楚地做到这一点。这导致了分配函数的发展,该函数描述了分子量子态的分布与独立的宏观热力学性质之间的关系。

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