Small-Molecule Spectroscopy and Dynamics

开始时间: 01/01/2014 持续时间: 未知

所在平台: MIT OCW

课程类别: 化学

大学或机构: ocw

   

课程主页: http://ocw.mit.edu/courses/chemistry/5-80-small-molecule-spectroscopy-and-dynamics-fall-2008

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课程简介

The goal of this course is to illustrate the spectroscopy of small molecules in the gas phase: quantum mechanical effective Hamiltonian models for rotational, vibrational, and electronic structure; transition selection rules and relative intensities; diagnostic patterns and experimental methods for the assignment of non-textbook spectra; breakdown of the Born-Oppenheimer approximation (spectroscopic perturbations); the stationary phase approximation; nondegenerate and quasidegenerate perturbation theory (van Vleck transformation); qualitative molecular orbital theory (Walsh diagrams); the notation of atomic and molecular spectroscopy.

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